Thermodynamics & Kinetics
Spring 2008
Course Description
Acknowledgements
The material for 5.60 has evolved over a period of many years, and therefore several faculty members have contributed to the development of the course contents. The following are known to have assisted in preparing the lecture notes available on OpenCourseWare:
Emeritus Professors of Chemistry: Robert A. Alberty, Carl W. Garland, Irwin Oppenheim, John S. Waugh.
Professors of Chemistry: Moungi Bawendi, John M. Deutch, Robert W. Field, Robert G. Griffin, Keith A. Nelson, Robert J. Silbey, Jeffrey I. Steinfeld.
Professor of Bioengineering and Computer Science: Bruce Tidor.
Professor of Chemistry, Rice University: James L. Kinsey.
Professor of Physics, University of Illinois: Philip W. Phillips.
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Lecture Notes
The lecture handouts are available in the table below. Please note that there were no lecture notes for session #36.
| SES # | TOPICS | LECTURE NOTES |
|---|---|---|
| 1 | State of a system, 0th law, equation of state | (PDF) |
| 2 | Work, heat, first law | (PDF) |
| 3 | Internal energy, expansion work | (PDF) |
| 4 | Enthalpy | (PDF) |
| 5 | Adiabatic changes | (PDF) |
| 6 | Thermochemistry | (PDF) |
| 7 | Calorimetry | (PDF) |
| 8 | Second law | (PDF) |
| 9 | Entropy and the Clausius inequality | (PDF) |
| 10 | Entropy and irreversibility | (PDF) |
| 11 | Fundamental equation, absolute S, third law | (PDF) |
| 12 | Criteria for spontaneous change | (PDF) |
| 13 | Gibbs free energy | (PDF) |
| 14 | Multicomponent systems, chemical potential | (PDF) |
| 15 | Chemical equilibrium | (PDF) |
| 16 | Temperature, pressure and Kp | (PDF) |
| 17 | Equilibrium: application to drug design | (PDF) |
| 18 | Phase equilibria — one component | (PDF) |
| 19 | Clausius-Clapeyron equation | (PDF) |
| 20 | Phase equilibria — two components | (PDF) |
| 21 | Ideal solutions | (PDF) |
| 22 | Non-ideal solutions | (PDF) |
| 23 | Colligative properties | (PDF) |
| 24 | Introduction to statistical mechanics | (PDF) |
| 25 | Partition function (q) — large N limit | (PDF) |
| 26 | Partition function (Q) — many particles | (PDF) |
| 27 | Statistical mechanics and discrete energy levels | |
| 28 | Model systems | (PDF) |
| 29 | Applications: chemical and phase equilibria | (PDF) |
| 30 | Introduction to reaction kinetics | (PDF) |
| 31 | Complex reactions and mechanisms | (PDF) |
| 32 | Steady-state and equilibrium approximations | (PDF) |
| 33 | Chain reactions | (PDF) |
| 34 | Temperature dependence, Ea, catalysis | (PDF) |
| 35 | Enzyme catalysis | (PDF) |
| 36 | Autocatalysis and oscillators |
Video Lectures
Special software is required to use some of the files in this section: .mp4.
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